Magister Negi Magi wear maid outfits for typically no purpose at all; primarily with the, as is widespread, Robot Girl Chachamaru . For Chachamaru there's justification, she is Evangeline's servant. The other women, properly the excuse was that they'd simply taken a bath and wanted clear clothes (they had been in Evangeline's resort on the time).Because he can't help however have things be clear, he...
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Misaki from Kaichou wa Maid-sama is a classic example of a maid that popularized tropes in addition to subverted them. Although she is more of a tsundere in the course of Takumi, she treats her prospects with respect and the utmost customer service, until you do anything unruly, after all. Mey-Rin from Black Butler may seem like a ditzy maid who can't do her job, and you're precisely right. Her function as...